eesti teaduste
akadeemia kirjastus
SINCE 1952
Proceeding cover
of the estonian academy of sciences
ISSN 1736-7530 (Electronic)
ISSN 1736-6046 (Print)
Impact Factor (2022): 0.9
Behaviour of thermal expansion of (1-x)Pb(Ni1/3Nb2/3)O3xPbTiO3 solid solutions; pp. 363–371

Karlis Bormanis, Mikhail G. Gorev, Igor N. Flerov, Andris Sternberg, Lelde Lace, Reinis Ignatans, Anna Kalvane, Maija Antonova

The features of the dependence of the bulk coefficient of thermal expansion of the (1-x)Pb(Ni1/3Nb2/3)O3xPbTiO3 solid solution studied in the series of x = 0–0.8 in the temperature range from 100 to 750 K are reported. The obtained data and observed anomalies of thermal expansion are compared with dielectric properties, heat capacity, and the phase diagram of concentration. The anomalous and lattice constituents of deformation and of the coefficient of thermal expansion are analysed and the data on deformation are used to estimate the Burns temperature and the mean square polarization of the samples found to decrease with the decrease of the PbTiO3 concentration.


    1. Singh, S. P., Singh, A. K., Pandey, D., and Yusuf, S. M. Dielectric relaxation and phase transitions at cryogenic temperatures in 0.65[Pb(Ni1/3Nb2/3)O3]–0.35PbTiO3 ceramics. Phys. Rev. B, 2007, 76, 054102.

    2. Tsukada, S., Ike, Y., Kano, J., Sekiya, T., Shimojo, Y., Wang, R., and Kojima, S. Dynamical properties of polar nanoregions of relaxor ferroelectric Pb(Ni1/3Nb2/3)O3–0.29PbTiO3. J. Phys. Soc. Jpn., 2008, 77, 33707.

    3. Pan, Z., Chen, J., Fan, L., Wang, Q., Liu, L., Fang, L., and Xing, X. Both electric field and temperature independent behavior of piezoelectric property of Pb(Ni1/3Nb2/3)O3–PbTiO3. Mat. Res. Bull., 2015, 61, 448–452.

    4. Peng, B., Zhang, Q., Ke, S., Li, T., Niu, H., Zeng, X., and Huang, H. Large electrocaloric strength in the (100)-oriented relaxor ferroelectric Pb[(Ni1/3Nb2/3)0.6Ti0.4]O3 single crystal at near morphotropic phase boundary. Ceram. Int., 2015, 41, 9344–9349.

    5. Smolensky, G. А. and Аgranovskaya, А. I. Dielectric polarisation and losses of complex compounds. Zh. Tekhnicheskoy. Fiz., 1958, 28(7), 1491–1493 (in Russian).

    6. Shirakami, T., Mitsukawa, M., Imai, T., and Urabe, K. A new method of determining short-range order parameter in relaxor Pb(Ni1/3Nb2/3)O3 by magnetic susceptibility measurement. Jpn. J. Appl. Phys., 2000, 39, Part 2, L678.

    7. Jona, F. and Shirane, G. Ferroelectric Crystals. Pergamon Press, Oxford–London–New York–Paris, 1962.

    8. Smolensky, G. А., Вokov, V. А., Isupov, V. А., Krajnik, N. N., Pasynkov, R. E., and Shur, M. S. Ferroelectrics and Antiferroelectrics. Nauka, Moscow, 1971 (in Russian).

    9. Lei, C., Chen, K., Zhang, X., and Wang, J. Study of the structure and dielectric relaxation behavior of Pb(Ni1/3Nb2/3)–PbTiO3 ferroelectric ceramics. Solid State Commun., 2002, 123, 445–450.

 10. Lei, C., Chen, K., and Zhang, X. Dielectric and ferro­electric properties of Pb(Ni1/3Nb2/3)O3–PbTiO3 ferro­electic ceramic near the morphotropic phase boundary. Mater. Lett., 2002, 54, 8–12.

 11. Tsukada, S., Ike, Y., Kano, J., Sekiya, T., and Shimojo, Y. Broadband inelastic light scattering of a relaxor ferroelectric 0.71Pb(Ni1∕3Nb2∕3)O3–0.29PbTiO3. Appl. Phys. Lett., 2006, 89, 212903.

 12. Fang, B., Wu, D., Du, Q., Zhou, L., and Yan, Y. Structure and electrical properties of oxide doped rhombohedral Pb(Ni1/3Nb2/3)O3–PbTiO3 ferroelectric ceramics. Mater. Sci. Appl., 2010, 1, 66–71.

 13. Kallaev, S. N., Bilalov, A. R., Ferzilaev, R. M., Omarov, Z. M., Bormanis, K., and Sadykov, S. M. Dielectric properties and heat capacity of ferroelectric ceramics (1‑x)PbNi1/3Nb2/3O3xPbTiO3. Fizika Tverdogo Tela, 2012, 54, 1716–1718 (in Russian; English trans­lation: Dielectic properties and specific heat of the (1-x)PbNi1/3Nb2/3O3xPbTiO3 ferroelectic ceramics. Physics of the Solid State, 54, 1829–1831).

 14. Kallaev, S. N., Omarov, Z. M., Mitarov, R. G., and Bormanis, K. Heat capacity of ferroelectric ceramics 0.7PbNi1/3Nb2/3O3-0.3PbTiO3. Fizika Tverdogo Tela, 2012, 54, 1905–1908 (in Russian; English translation: Heat capacity of the 0.7PbNi1/3Nb2/3O3-0.3PbTiO3 ferroelectic ceramics. Physics of the Solid State, 54, 2030–2033).

 15. Kallaev, S. N., Bormanis, K., Omarov, Z. M., Mitarov, R. G., and Kalvane, A. Thermal properties of ferroelectric 0.7PbNi1/3Nb2/3O3–0.3PbTiO3 ceramics. Phase Transit., 2013, 86, 886–892.

 16. Mikhaleva, E. A., Flerov, I. N., Gorev, M. V., Molokeev, M. S., Cherepakhin, A. V., Kartashev A. V., et al. Caloric characteristics of PbTiO3 at ferroelectric phase transition. Fizika Tverdogo Tela, 2012, 54, 1719–1726 (in Russian; English translation: Caloric characteristics of PbTiO3 in the temperature range of the ferroelectric phase transition. Physics of the Solid State, 2012, 54, 1832–1840).

 17. Cann, N. Preparation and ferroelectric properties of pyrochlore-free Pb(Ni1/3Nb2/3)O3-based solid solutions. Appl. Phys. A, 2006, 86(3), 403–408.

 18. Araújo, E. B. Recent advances in processing, structural and dielectric properties of PMN-PT ferroelectric ceramics at compositions around the MPB. In Advances in Ceramics Electric and Magnetic Ceramics, Bioceramics, Ceramics and Environment (Sikalidis, C., ed.). InTech, Rijeka, Croatia, 2011, 43–60.

 19. Khamman, O., Yimnirun, R., Sirikulrat, N., and Ananta, S. Phase formation and transitions in the lead nickel niobate-lead zirconate titanate system. Ceram. Int., 2012, 38, Suppl. 1, 17–20.

 20. Li, Y., Li, J., Zhou, Z., Guo, R., and Bhalla, A. Thermal expansion behavior and polarization properties of lead-free ferroelectric potassium lithium tantalate niobate single crystals. Ceram. Int., 2014, 40, 1225–1228.

 21. Unruan, M., Prasatkhetragarn, A., Laosiritaworn, Y., Ananta, S., Khamman, O., Yimnirun, R., and Bhalla, A. Thermal expansion behavior and estimated total polari­zations of lead zirconate titanate–lead nickel niobate ceramics. Mater. Lett., 2010, 64, 1960–1963.

 22. Wongmaneerung, R., Guo, R., Bhalla, A., Yimnirun, R., and Ananta, S. Thermal expansion properties of PMN–PT ceramics. J. Alloy. Comp., 2008, 461, 565–569.

 23. Wongsaenmai, S., Yimnirun, R., Ananta, S., Guo, R., and Bhalla, A. Thermal expansion measurements in the relaxor ferroelectric PIN–PT system. Mater. Lett., 2008, 62, 352–356.

 24. Fesenko, E. G., Gavrilyachenko, V. G., and Zarochentsev, E. V. Ferroelectric properties of lead titanate single crystals. Izvestiya AN SSSR, Ser. Fiz., 1970, 34(12), 2541–2549 (in Russian).

 25. Gavrilyachenko, V. G., Spinko, R. I., Martynenko, M. A., and Fesenko, E. G. Spontaneous polarization and coercive field in lead titanate. Fizika Tverdogo Tela, 1970, 5, 1532–1534 (in Russian).

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