The recent changes in the European Union Wastewater Directive require micropollutant elimination from the effluents of wastewater treatment plants serving at least 150 000 population equivalents, and in some cases even starting from 10 000. While ozonation can degrade micropollutants without secondary wastes, the treated effluent composition must be considered, specifically the concentration of bromide (Br–). Depending on its amount and oxidant dose, bromide can potentially be oxidised to carcinogenic bromate (BrO3–). This research investigates bromide amounts in the effluents of Estonian wastewater treatment plants serving at least 10 000 population equivalents as preliminary work for quaternary wastewater treatment aimed at micropollutant removal.
Asgari, G., Samiee, F., Ahmadian, M., Poormohammadi, A. and Solimanzadeh, B. 2017. Catalytic ozonation of pentachlorophenol in aqueous solutions using granular activated carbon. Applied Water Science, 7, 393–400.
https://doi.org/10.1007/s13201-014-0254-y
Chowdhury, S., Koyappathody, T. M. F. and Karanfil, T. 2022. Removal of halides from drinking water: technological achievements in the past ten years and research needs. Environmental Science and Pollution Research, 29, 55514‒55527.
https://doi.org/10.1007/s11356-022-21346-z
CWPharma. 2020. Guideline for advanced API removal: optimisation and control of advanced treatment.
https://evel.ee/wp-content/uploads/2021/01/CWP_Guideline_GOA3_4_Final.pdf (accessed 2025-06-11).
European Union. 2020. Directive (EU) 2020/2184 of the European Parliament and of the Council of 16 December 2020 on the quality of water intended for human consumption (recast).
https://eur-lex.europa.eu/legal-content/EN/TXT/?uri=celex%3A32020L2184 (accessed 2025-05-26).
European Union. 2024. Directive of the European Parliament and of the Council concerning urban wastewater treatment (recast).
https://data.consilium.europa.eu/doc/document/PE-85-2024-INIT/en/pdf (accessed 2024-11-08).
Gallard, H., Pellizarri, F., Croué, J. P. and Legube, B. 2003. Rate constants of reactions of bromine with phenols in aqueous solution. Water Research, 37(12), 2883‒2892.
https://doi.org/10.1016/S0043-1354(03)00132-5
Haag, W. R. and Hoigne, J. 1983. Ozonation of bromide-containing waters: kinetics of formation of hypobromous acid and bromate. Environmental Science & Technology, 17(5), 261‒267.
https://doi.org/10.1021/es00111a004
Heeb, M. B., Kristiana, I., Trogolo, D., Arey, J. S. and von Gunten, U. 2017. Formation and reactivity of inorganic and organic chloramines and bromamines during oxidative water treatment. Water Research, 110, 91‒101.
https://doi.org/10.1016/j.watres.2016.11.065
Hoigne, J. and Bader, H. 1978. Ozonation of water: kinetics of oxidation of ammonia by ozone and hydroxyl radicals. Environmental Science & Technology, 12(1), 79‒84.
https://doi.org/10.1021/es60137a005
Hu, W., Lee, Y. and Allard, S. 2021. Kinetics and mechanistic investigations of the decomposition of bromamines in the presence of Cu(II). Water Research, 207, 117791.
https://doi.org/10.1016/j.watres.2021.117791
Johannesson, J. K. 1960. The bromination of swimming pools. American Journal of Public Health, 50, 1731‒1736.
https://doi.org/10.2105/AJPH.50.11.1731
Karro, E., Marandi, A. and Vaikmäe, R. 2004. The origin of increased salinity in the Cambrian‒Vendian aquifer system on the Kopli Peninsula, northern Estonia. Hydrogeology Journal, 12, 424‒435.
https://doi.org/10.1007/s10040-004-0339-z
Karro, E., Marandi, A., Vaikmäe, R. and Uppin, M. 2009. Chemical peculiarities of the Silurian‒Ordovician and Cambrian‒Vendian aquifer systems in Estonia: an overview of hydrochemical studies. Estonian Journal of Earth Sciences, 58(4), 342‒352.
https://doi.org/10.3176/earth.2009.4.12
Karro, E., Veeperv, K., Hiiob, M. and Uppin, M. 2020. The occurrence and geological sources of naturally high iron in the Middle Devonian aquifer system, Estonia. Estonian Journal of Earth Sciences, 69(4), 281–294.
https://doi.org/10.3176/earth.2020.17
Klauson, D., Kivi, A., Kattel, E., Klein, K., Viisimaa, M., Bolobajev, J. et al. 2015. Combined processes for wasterwater purification: treatment of a typical landfill leachate with a combination of chemical and biological oxidation processes. Journal of Chemical Technology and Biotechnology, 90, 1527−1536.
https://doi.org/10.1002/jctb.4484
Klauson, D., Romero Sarcos, N., Krichevskaya, M., Kattel, E., Dulova, N., Dedova, T. et al. 2019. Advanced oxidation processes for sulfonamide antibiotic sulfamethizole degradation: process applicability study at ppm level and scale-down to ppb level. Journal of Environmental Chemical Engineering, 7(5), 103287.
https://doi.org/10.1016/j.jece.2019.103287
Klein, K., Kattel, E., Goi, A., Kivi, A., Dulova, N., Saluste, A. et al. 2017. Combined treatment of pyrogenic wastewater from oil shale retorting. Oil Shale, 34(1), 82‒96.
https://doi.org/10.3176/oil.2017.1.06
Mestri, S., Dogan, S. and Tizaoui, C. 2023. Bromate removal from water using ion exchange resin: batch and fixed bed column performance. Ozone: Science & Engineering, 45(3), 291‒304.
https://doi.org/10.1080/01919512.2022.2114420
Morrison, C. M., Hogard, S., Pearce, R., Mohan, A., Pisarenko, A. N., Dickenson, E. R. V. et al. 2023. Critical review on bromate formation during ozonation and control options for its minimization. Environmental Science & Technology, 57(47), 18393−18409.
https://doi.org/10.1021/acs.est.3c00538
Odeh, I. N., Nicoson, J. S., Huff Hartz, K. E. and Margerum, D. W. 2004. Kinetics and mechanisms of bromine chloride reactions with bromite and chlorite ions. Inorganic Chemistry, 43(23), 7412−7420.
https://doi.org/10.1021/ic048982m
Perrin, D. D. (ed.) 1982. Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution. IUPAC Chemical Data. 2nd ed. Pergamon Press, Oxford.
PubChem. Phenol (compound).
https://pubchem.ncbi.nlm.nih.gov/compound/Phenol#section=Refractive-Index (accessed 2025-12-02).
Sarron, E., Gadonna-Widehem, P. and Aussenac, T. 2021. Ozone treatments for preserving fresh vegetables quality: a critical review. Foods, 10(3), 605.
https://doi.org/10.3390/foods10030605
Tenno, T., Rikmann, E., Zekker, I. and Tenno, T. 2018. Modelling the solubility of sparingly soluble compounds depending on their particles size. Proceedings of the Estonian Academy of Sciences, 67(3), 300‒302.
https://doi.org/10.3176/proc.2018.3.10
Trapido, M., Tenno, T., Goi, A., Dulova, N., Kattel, E., Klauson, D. et al. 2017. Bio-recalcitrant pollutants removal from wastewater with combination of the Fenton treatment and biological oxidation. Journal of Water Process Engineering, 16, 277−282.
https://doi.org/10.1016/j.jwpe.2017.02.007
Water News Europe. Global database of WWTPs and their effluents.
https://www.waternewseurope.com/global-database-wwtps/ (accessed 2024-11-11).
WHO (World Health Organization). 2018. Bromine as a drinking-water disinfectant.
https://cdn.who.int/media/docs/default-source/wash-documents/wash-chemicals/bromine-02032018.pdf?sfvrsn= 8890aff_3 (accessed 2026-02-12).
Wu, Q.-Y., Zhou, Y.-T., Li, W., Zhang, X., Du, Y. and Hu, H.-Y. 2019. Underestimated risk from ozonation of wastewater containing bromide: both organic byproducts and bromate contributed to toxicity increase. Water Research, 162, 43‒52.
https://doi.org/10.1016/j.watres.2019.06.054