ESTONIAN ACADEMY
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eesti teaduste
akadeemia kirjastus
PUBLISHED
SINCE 1952
 
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proceedings
of the estonian academy of sciences
ISSN 1736-7530 (Electronic)
ISSN 1736-6046 (Print)
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A new method for the synthesis of 3-hydrazinopropyl trimethoxysilane; pp. 64–68
PDF | doi: 10.3176/proc.2011.1.07

Authors
Kaija Põhako, Kristjan Saal, Aleksei Bredihhin, Ilmar Kink, Uno Mäeorg
Abstract
A new method for the synthesis of 3-hydrazinopropyl trimethoxysilane is proposed. The method is relatively simple and is based on hydrosilylation like the synthesis of analogous aminosilanes. For drying allylhydrazine hydrate a new efficient silyl hydride base method is proposed. The product, a new hydrazino-ormosil (organically modified silicate), can be applied in chemical modification of SiO2 surfaces, thus offering an alternative to aminosilane modification, which is widely applied in several surface coating technologies.
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