Abstract


SUPERCRITICAL CARBON DIOXIDE EXTRACTION OF ESTONIAN OIL SHALE

M. KOEL, S. LJOVIN, Ye. BONDAR
Institute of Chemistry, Tallinn Technical University
15 Akadeemia St., Tallinn, 12618 Estonia

Results on the application of supercritical carbon dioxide extraction (SFE) at different temperatures are presented, and comparison with classical Soxhlet chloroform extracts is made. Pure carbon dioxide extracted preferably n-alkanes, whereas modifying of the fluid with methanol inten-sified the extraction of more polar compounds and increased as a result total yield of extract. Increasing of SFE temperature had the same influence on the yield of extract, however, already at 200 °C partial heterolytic cracking of the kerogen of kukersite started. The similarity of composition and relative distribution of n-alkanes, n-alkanones-2, n-alkylbenzenes and n-alkylcyclohexanes in both SFE and Soxhlet extracts of kukersite was observed.

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