Fly ash as an adsorbent for the removal of reactive blue 25 dye from aqueous solutions: optimization, kinetic and isotherm investigations; pp. 300–308Full article in PDF format | https://doi.org/10.3176/proc.2017.3.10
Fly ash obtained from a thermal power station was used as an adsorbent for the adsorption of reactive blue 25 dye from aqueous solutions. The parameters affecting the batch adsorption studies were optimized for this system. Lagergren’s kinetic models were used for the analysis of the kinetics of dye adsorption by fly ash. It was observed that dye adsorption followed pseudo-second-order kinetics. Batch adsorption experimentation data were fitted to two well-known isotherms: the Langmuir and Freundlich models. Regression analysis showed a good fit of the Freundlich isotherm model. Based on the adsorption studies it can be concluded that the fly ash can be used as effectual adsorbent for the removal of dye from aqueous solutions.
Aksu, Z. M. and Isoglu, I. A. 2006. Use of agricultural waste sugar beet pulp for the removal of Gemazol turquoise blue-G reactive dye from aqueous solution. J. Hazard. Mater., 137, 418–430.
APHA. 1980. Standard Methods for the Examination of Water and Wastewater. American Public Health Association, Washington, DC.
Argun, M. E., Guclu, D., and Karatas, M. 2014. Adsorption of Reactive Blue 114 dye by using a new adsorbent: pomelo peel. J. Ind. Eng. Chem., 20, 1079–1084.
Aygun, A., Yenisoy-Karakas, S., and Duman, I. 2003. Production of granular activated carbon from fruit stones and nutshells and evaluation of their physical, chemical and adsorption properties. Microporous Mesoporous Mater., 66, 189–195.
Bhatnagar, A. and Jain, A. K. 2005. A comparative adsorption study with different industrial wastes as adsorbents for the removal of cationic dyes from water. J. Colloid Interf. Sci., 281, 49–55.
Convery, M., Downing, L., Yin, C. Y., Goh, B. M., and Sharifah, A. S. A. K. 2010. Characterization of glass-ceramics produced from vitrification of class F Malaysian coal fly ash. Int. J. Mech. Mater. Eng., 5, 1–4.
Freundlich, H. 1906. Adsorption in solution. Phys. Chem. Soc., 40, 1361–1368.
Ho, Y. S. and McKay, G. 1999. Pseudo-second order model for sorption processes. Process. Biochem., 34, 451–465.
Irem, S., Khan, Q. M., Islam, E., Hashmat, A. J., Anwar ul Haq, M., Afzal, M., and Mustafa, T. 2013. Enhanced removal of reactive navy blue dye using powdered orange waste. Ecol. Eng., 58, 399–405.
Kadirvelu, K., Kavipriya, M., Karthika, C., Radhika, M., Vennilamani, N., and Pattabhi, S. 2003. Utilization of various agricultural wastes for activated carbon preparation and application for the removal of dyes and metal ions from aqueous solutions. Bioresource Technol., 87, 129–132.
Lagergren, S. 1898. Zur Theorie der sogenannten Adsorption geloster Stoffe [About the theory of so-called adsorption of soluble substances]. K. Sven. Vetenskapsakad Handl., 24, 1–39.
Langmuir, I. 1918. The adsorption of gases on plane surfaces of glass, mica and platinum. J. Am. Chem. Soc., 40, 1361–1403.
Lee, C. K., Low, K. S., and Gan, P. Y. 1999. Removal of some organic dyes by acid-treated spent bleaching earth. Environ. Technol., 20, 99–104.
Malik, P. K. 2003. Use of activated carbons prepared from sawdust and rice-husk for adsorption of acid dyes: a case study of acid yellow 36. Dyes Pigm., 56, 239–249.
Namasivayam, C., Prabha, D., and Kumutha, M. 1998. Removal of direct red and acid brilliant blue by asorption onto banana pith. Bioresource Technol., 64, 77–79.
Narkis, N. and Ben-David, B. 1985. Adsorption of non-ionic surfactants on activated carbon and mineral clay. Water Res., 19, 815–824.
Ofomaja, A. E. and Ho, Y. S. 2008. Effect of tempera-tures and pH on methyl violet biosorption by Mansonia wood sawdust. Bioresource Technol., 99, 5411–5417.
Orumwense, F. F. O. 1996. Removal of lead from water by adsorption on a kaolinitic clay. J. Chem. Tech. Biotechnol., 65, 363–369.
Papic, S., Koprivanac, N., and Metes, A. 2000. Optimizing polymer-induced flocculation process to remove reactive dyes from wastewater. Environ. Technol., 21, 97–105.
Rajeshwari, S., Namasivayam, C., and Kadirvelu, K. 2001. Orange peel as an adsorbent in the removal of acid violet 17 (acid dye) from aqueous solutions. Waste Manage., 21, 105–110.
Salleh, M. A. M., Mahmoud, D. K., Karim, W. A., and Idris, A. 2011. Cationic and anionic dye adsorption by agricultural solid wastes: a comprehensive review. Desalination, 280, 1–13.
Senapati, M. R. 2011. Fly ash from thermal power plants – waste management and overview. Curr. Sci., 100, 1791–1794.
Sharma, Y. C. and Upadhyay, S. N. U. 2009. Removal of a cationic dye from wastewaters by adsorption on activated carbon developed from coconut coir. Energy Fuels, 23, 2983–2988.
Singh, M. 2015. Report on Fly Ash Generation at Coal/Lignite Based Thermal Power Stations and its Utilization in the Country for the Year 2014–15. Central Electricity Board, New Delhi.
Reddy, M. C., Nirmala, V., and Ashwini, C. 2014. Bengal gram seed husk as an adsorbent for the removal of dye from aqueous solutions. Batch studies. Arab. J. Chem. doi:10.1016/j.arabjc.2013.09.029.
Sun, D., Zhang, Z., Wang, M., and Wu, Y. 2013. Adsorption of reactive dyes on activated carbon developed from Enteromorpha prolifera. Am. J. Analyt. Chem., 4, 17–26.
Tabak, A., Eren, E., Afsin, B., and Caglar, B. 2009. Determination of adsorptive properties of a Turkish sepiolite for removal of reactive blue 15 anionic dye from aqueous solutions. J. Hazard. Mater., 161, 1087–1094.
Yin, C. Y., Aroua, M. K., and Daud, W. M. A. W. 2008. Enhanced adsorption of metal ions onto polyethyleneimine-impregnated palm shell activated carbon: equilibrium studies. Water Air Soil Poll., 192, 337–348.
Yin, C. Y., Aroua, M. K., and Daud, W. M. A. W. 2009. Fixed-bed adsorption of metal ions from aqueous solution on polyethyleneimine-impregnated palm shell activated carbon. Chem. Eng. J., 148, 8–14.
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