ESTONIAN ACADEMY
PUBLISHERS
eesti teaduste
akadeemia kirjastus
PUBLISHED
SINCE 1984
 
Oil Shale cover
Oil Shale
ISSN 1736-7492 (Electronic)
ISSN 0208-189X (Print)
Impact Factor (2022): 1.9
RESOURCES, PRODUCTION AND PROCESSING OF BALTOSCANDIAN MULTIMETAL BLACK SHALES; pp. 68–77
PDF | doi: 10.3176/oil.2011.1.08

Authors
Endel Lippmaa, Ello Maremäe, A.-T. PIHLAK
Abstract
It has been generally accepted that black shales are oil shales and have to be handled as sources of fuel oil. This attitude has been so prevalent that it is applied even to those thermally mature black shales in Jämtland (Sweden) and Sillamäe (Estonia) that supply practically no oil on thermal treatments even in the presence of hydrogen. It may well be that these shales are a very significant source not for oil and not only for uranium, but for valuable metals in general, including molybdenum, rhenium and many others. A new, hydrogenation-based technology may be necessary in this case.
References

  1. Bromley-Challenor, M., Godin, E., Jackson, S. A., Sheahan, P., Snäll, S. Energy independence for Europe: 2009 update on development of the Cambrian alum shale of Sweden, a world class energy resource for oil and uranium // Continental Precious Minerals Inc. Sweden, International Oil Shale Symposium, Tallinn, June 8–11, 2009.

  2. Krenkel, H., Bromley-Challenor, M., Snäll, S. Evaluation of liquid hydro­carbon recovery potential from Swedish alum shale // Alberta Research Council, Canada, Continental Precious Minerals Inc. Sweden, International Oil Shale Symposium, Tallinn, Estonia, June 8–11, 2009.

  3. Bergius, F., Billwiller, J. Verfahren zur Herstellung von flüssigen oder löslichen organischen Verbindungen aus Steinkohle und dergleichen, DE 301231, 1913/1919.

  4. Pier, M. Behandlung von Schieferöl durch Hydrierung, Österreichische Chemiker-Zeitung, 1939. Vol 2, P. 33–39.

  5. Janka, J. C. The HYTORT process: a new approach to Swedish oil shales // HYCRUDE Corporation, Chicago, Illinois USA, December 13, 1983.

  6. News Blaze, Continental Precious Minerals provide update to Economic Scoping Study. Published April 08, 2010.

  7. Treibs, A. Chlorophyll- und Häminderivate in bituminösen Gesteinen // Annalen. 1934. Vol. 509. P. 108.

  8. AGAL, Plant derived minerals: The Reference // Contact International P/L.

  9. Beleites, M. Pechblende / Der Uranbergbau in der DDR und seine Folgen. KFH1 –. 1988. P. 65.

10. Gukov, F. Ya. Technical passport of the Chemical Factory No 1 and the Complex of the Integrated Plant No 7 about the situation at 01.01.1951 / Strictly confidential, to be kept indefinitely, on 77 pages [in Russian].

11. Strandell, E. A. Uran ur skiffer Ranstadsverket 40 års utveckling av processer för utvinning av uran ur mellansvenska alunskiffrar. Första delen utvecklingen av AE-processen // Ranstad TPM 1534. 1992. P. 536.

12. Lüschen, H. Vergleichende anorganisch-geochemische Untersuchungen an phanerozoischer Corg-reichen Sedimenten: Ein Beitrag zur Characterisierung ihrer Fazies // Doktordissertation, Carl von Ossietzky Universität Oldenburg. 2004. P. 392.

13. Lupander, K. Sv patent 307926. Sätt att uttvinna värdefulla producter ur skiffer och andra bituminösa material // Atomenergie. 1963.07.15.

14. Althausen, M., Maremäe, E., Johannes, E., Lippmaa, E. Weathering of metalli­ferous alum shales // Proc. Acad. Sci. Estonia. Chem. 1980. Vol. 29, No. 3. P. 165–169.

15. Norman, R. E. Uranium production in Eastern Europe and its enviromental impact: a literature survey // ORNL/TM – 12240, Oak Ridge National Laboratory. April 1993.

16. Kallaste, T. Inst. Geology of Tallinn University of Technology. Tallinn, 2009, personal communication.

17. Raukas, A., Teedumäe, A. Geology and mineral resources of Estonia // Estonian Academy publishers. Tallinn, 1997. P. 436.

18. Boitsov, A., Capus, G., Dahlkamp, F. J., Kidd, S., Klassen, G., McMurray, J. M., Miyada, H., Shani, R., Szymanski, W. N., Underhill, D. H., Vera, I. Analysis of uranium supply to 2050 // 2110 International Atomic Energy Agency. 2001. P. 103.

19. Fox, D. L. Biochromy, natural coloration of living things // University of California Press. 1979. P. 163 (“Alfred Treibs found porphyrins in early 1930’s in very ancient Esthonian fire shales”).

20. Jorger, G. A., Garcia, E., Scott, C. E. Electrolysis of Vanadium (IV) and free meso-tetraphenyl porphyrin in two immiscible liquids // J. Appl. Electrochem. 2002. Vol. 32. P. 569–572.
doi:10.1023/A:1016594110625

21. Baez, V., D’Elia, L. F., Rodriguez, G., Intevep, S. A. Process for treating hydrocarbon feeds with electrolytic hydrogen // US Patent Application No. 11/650 083. 2007.

22. Burnham, A. K., McConaghy, J. R. Comparison of the Acceptability of various oil shale processes // UCRL–CONF–226717, 26th Oil Shale Symposium, Golden, USA, October 2006.
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