Estonia’s basic power supply is covered mainly by oil shale-fired thermal power plants. The pulverized combustion (PC) and circulating fluidized bed combustion (CFBC) technologies are used. The power plant exploitation has revealed the emission of gaseous pollutants, as well as ash handling problems. The hydro ash removal is used at large power plants in Estonia. An overview of the formation and properties of oil shale ash is given. The polluting impact of ash in contact with water is analyzed. Taking into account precipitation and evaporation conditions the amount of water bound by ash as well as ash field water balance is given. The leaching behaviour of oil shale ash is analyzed. The analysis of the ash field structure shows that the degree of water penetration of the ash field body meets the requirements for hazardous waste landfills. The water permeability through dense layers ranges from 0.15 × 10–9 to 16.1 × 10–9 m/s.
1. Konist, A., Maaten, B., Loo, L., Neshumayev, D., Pihu, T. Mineral sequestration of CO2 by carbonation of Ca-rich oil shale ash in natural conditions. Oil Shale, 2016, 33(3), 248−259.
https://doi.org/10.3176/oil.2016.3.04
2. Loo, L., Maaten, B., Konist, A., Siirde, A., Neshumayev, D., Pihu, T. Carbon dioxide emission factors for oxy-fuel CFBC and aqueous carbonation of the Ca-rich oil shale ash. Energy Procedia, 2017, 128, 144−149.
https://doi.org/10.1016/j.egypro.2017.09.034
3. Pihu, T., Konist, A., Neshumayev, D., Loo, L., Molodtsov, A., Valtsev, A. Full-scale tests on the co-firing of peat and oil shale in an oil shale fired circulating fluidized bed boiler. Oil Shale, 2017, 34(3), 250−262.
https://doi.org/10.3176/oil.2017.3.04
4. Konist, A., Valtsev, A., Loo, L., Pihu, T., Liira, M., Kirsimäe, K. Influence of oxy-fuel combustion of Ca-rich oil shale fuel on carbonate stability and ash composition. Fuel, 2015, 139, 671−677.
https://doi.org/10.1016/j.fuel.2014.09.050
5. Konist, A, Pihu, T, Neshumayev, D, Külaots, I. Low-grade fuel ̶ oil shale and biomass co-combustion in CFB boiler. Oil Shale, 2013, 30(2S), 294−304.
https://doi.org/10.3176/oil.2013.2S.09
6. Konist, A., Pihu, T., Neshumayev, D., Siirde, A. Oil shale pulverized firing: boiler efficiency, ash balance and flue gas composition. Oil Shale, 2013, 30(1), 6−18.
https://doi.org/10.3176/oil.2013.1.02
7. Ots, A. Oil Shale Fuel Combustion. Tallinna Raamatutrükikoda, Tallinn, 2006.
8. Directive 2010/75/EU of the European Parliament and of the Council of 24 November 2010 on Industrial Emissions (integrated pollution prevention and control). https://eur-lex-europa.eu/legal-content/EN/TXT/?uri= celex%3A32010L0075
9. Pihu, T., Arro, H., Prikk, A., Rootamm, R., Konist, A., Kirsimäe, K., Liira, M., Mõtlep, R. Oil shale CFBC ash cementation properties in ash fields. Fuel, 2012, 93, 172–180.
https://doi.org/10.1016/j.fuel.2011.08.050
10. Kuusik, R., Uibu, M., Kirsimäe, K., Mõtlep, R., Meriste, T. Open-air deposition of Estonian oli shale ash: formation, state of art, problems and prospects for the abatement of environmental impact. Oil Shale, 2012, 29(4), 376−403.
https://doi.org/10.3176/oil.2012.4.08
11. Arro, H., Prikk, A., Pihu, T. Calculation of qualitative and quantitative composition of Estonian oil shale and its combustion products. Part 1. Calculation on the basis of heating value. Fuel, 2003, 82(18), 2179−2195.
https://doi.org/10.1016/S0016-2361(03)00125-X
12. Konist, A., Pihu, T. Reducing CO2 emissions with oil shale circulating fluidized bed boiler ash. In: Proc. of the 21st Int. Conf. on Fluidized Bed Combustion, 2 (Editore, E. A., ed.). The 21st International Conference on Fluidized Bed Combustion, 3rd−6th June 2012, Naples, Italy.
13. Arro, H., Pihu, T., Prikk, A., Rootamm, R., Konist, A. Comparison of ash from PF and CFB boilers and behavior of ash in ash fields. In: Proc. of the 20th Int. Conf. on Fluidized Bed Combustion. II (Yue, G., Zhang, H., Zhao, C., Luo, Z, eds.). China, Xi’an, May 18−21, 2009. China, Tsinghua University Press/ Springer, 1054−1060.
https://doi.org/10.1007/978-3-642-02682-9_164
14. Arro, H., Prikk, A., Pihu, T. Reducing the environmental impact of Baltic Power Plant ash fields. Oil Shale, 2003, 20(3S), 375−382.
15. Certificate of Conformity CS No. 003697 of Estonian Plant Production Inspectorate, 11.09.2000 (in Estonian).
16. Hadi, N. A., Khoury, H. N., Suliman, M. S. Utilization of bituminous limestone ash from El-Lajjun area for engineering applications. Acta Geotech., 2008, 3(2), 139–151.
https://doi.org/10.1007/s11440-008-0063-2
17. Hadi, N. A. R. A., Abdelhadi, M. Characterization and utilization of oil shale ash mixed with granitic and marble wastes to produce lightweight bricks. Oil Shale, 2018, 35(1), 56–69.
https://doi.org/10.3176/oil.2018.1.04
18. Eesti Energia. Annual Report 2017. Environmental Report. https:// www.energia.ee/-/doc/8457332/ettevottest/investorile/pdf/annual_report_2017_ eng.pdf (retrieved on 06.11.2018).
19. Bityukova, L., Mõtlep, R., Kirsimäe, K. Composition of oil shale ashes from pulverized firing and circulating fluidized-bed boiler in Narva Thermal Power Plants, Estonia. Oil Shale, 2010, 27(4), 339–353.
https://doi.org/10.3176/oil.2010.4.07
20. Liira, M., Kirsimäe, K., Kuusik, R., Mõtlep, R. Transformation of calcareous oil-shale circulating fluidized-bed combustion boiler ashes under wet conditions. Fuel, 2009, 88(4), 712–718.
https://doi.org/10.1016/j.fuel.2008.08.012
21. Mõtlep, R., Sild, T., Puura, E., Kirsimäe, K. Composition, diagenetic transformation and alkalinity potential of oil shale ash sediments. J. Hazard. Mater., 2010, 184(1–3), 567−573.
https://doi.org/10.1016/j.jhazmat.2010.08.073
22. Ash Materials and Ash Fields (Melentjeva, V., ed.). Energiya, Moscow, 1978, 296 pp (in Russian).
23. Laja, M. Oil Shale Ash, Properties and Behaviour in Water Medium. Master Thesis, University of Tartu, 2005 (in Estonian).
24. Kahru, A., Sihtmäe, M. The Influence of the Eco-Toxicity of Product while Neutralizing – Carbonizing Oil Shale Ash by CO2. Research report, part 3. National Institute of Chemical Physics and Biophysics, Tallinn, 2007 (in Estonian).
25. Evaluation of Environmental Influence of Closure of Balti Power Plant’s Ash Field No. 2. Report. AS Maves, LHK, AS PIC Eesti, AS Merin. Tallinn, 2002 (in Estonian).
European Standard EN 12457-2. Characterization of Waste – Leaching – Compliance Test for Leaching of Granular Waste Materials and Sludges – Part 2. European Committee for Standardization Brussels, 2003.