As the world’s second largest solid fossil fuel deposit after coal, utilization of oil shale has become a research hotspot lately. The application of oil shale may be limited because of its high ash content. In this paper, froth flotation technology was used to treat oil shale. Oil shale samples were characterized by ultimate and proximate analyses. The collector was prepared using mechanical stirring and ultrasonic cell crusher methods. The dispersion of synthetic collectors was measured. When the mass ratio of kerosene to oleic acid was 1:1 and the agitation speed was 1800 rpm (hereinafter referred to as synthetic collector A), the dispersion property of the synthetic collector was the best, and the flotation results indicated that the flotation effect of synthetic collectors was improved. Collector adsorption measurements indicated that with increasing collector dosage, the adsorption quantity first increased and then leveled off at a dosage of 500 g/t. The infrared spectra of raw oil shale, kerosene, oleic acid and synthetic collector A were measured and the interactions between them were analyzed. The reasons for the good performance of synthetic collector A were found out.
1. Han, H., Zhong, N. N., Huang, C. X., Zhang, W. Pyrolysis kinetics of oil shale from northeast China: Implications from thermogravimetric and Rock-Eval experiments. Fuel, 2015, 159, 776–783.
https://doi.org/10.1016/j.fuel.2015.07.052
2. Jiang, H. F., Deng, S. H., Chen, J., Zhang, M. Y., Li, S., Shao, Y. F., Yang, J. Q., Li, J. F. Effect of hydrothermal pretreatment on product distribution and characteristics of oil produced by the pyrolysis of Huadian oil shale. Energ. Convers. Manage., 2017, 143, 505–512.
https://doi.org/10.1016/j.enconman.2017.04.037
3. Shi, W. J., Wang, Z., Song, W. L., Li, S. G.., Li, X. Y. Pyrolysis of Huadian oil shale under catalysis of shale ash. J. Anal. Appl. Pyrol. 2017, 123, 160–164.
https://doi.org/10.1016/j.jaap.2016.12.011
4. Bozkurt, P. A., Tosun, O., Canel, M. The synergistic effect of co-pyrolysis of oil shale and low density polyethylene mixtures and characterization of pyrolysis liquid. J. Energy Inst., 2017, 90(3), 355–362.
https://doi.org/10.1016/j.joei.2016.04.007
5. Saif, T., Lin, Q., Bijeljic, B., Blunt, M. J. Microstructural imaging and characterization of oil shale before and after pyrolysis. Fuel, 2017, 197, 562–574.
https://doi.org/10.1016/j.fuel.2017.02.030
6. Miao, Z. Y., Wu, G. G., Li, P., Meng, X. L., Zheng, Z. L. Investigation into co-pyrolysis characteristics of oil shale and coal. Int. J. Min. Sci. Technol., 2012, 22(2), 245–249.
https://doi.org/10.1016/j.ijmst.2011.09.003
7. Li, J. H., Cao, Z. B. Composition and comprehensive utilization of oil shale. Liaoning Chem. Ind., 2007, 36(6), 110–112 (in Chinese).
8. Olajossy, A. Some parameters of coal methane system that cause very slow release of methane from virgin coal beds (CBM). Int. J. Min. Sci. Technol., 2017, 27(2), 321–326.
https://doi.org/10.1016/j.ijmst.2017.01.006
9. Gupta, N. Evaluation of graphite depressants in a poly-metallic sulfide flotation circuit. Int. J. Min. Sci. Technol., 2017, 27(2), 285–292.
https://doi.org/10.1016/j.ijmst.2017.01.008
10. Tsai, S. C., Lumpkin, R. E. Oil shale beneficiation by froth flotation. Fuel, 1984, 63(4), 435–439.
https://doi.org/10.1016/0016-2361(84)90276-X
11. Altun, N. E., Hicyilmaz, C., Hwang, J. Y., Bagci, A. S. Evaluation of a Turkish low quality oil shale by flotation as a clean energy source: Material characterization and determination of flotation behavior. Fuel Process. Technol., 2006, 87(9), 783–791.
https://doi.org/10.1016/j.fuproc.2006.04.001
12. Altun, N. E., Hwang, J. Y., Hicyilmaz, C. Enhancement of flotation performance of oil shale cleaning by ultrasonic treatment. Int. J. Miner. Process., 2009, 91(1–2), 1–13.
https://doi.org/10.1016/j.minpro.2008.10.003
13. Xue, Q. H., Li, S. Y., Wang, H. Y., Zheng, D. W., Fang, C. H. Utilization of Daqing oil shale and its pyrolysis products. Sci. Technol. Chem. Ind., 2009, 17(3), 54–56 (in Chinese).
14. Hu, Y. H., Cao, X. F., Jiang, Y. R., Li, H. P., Du, P. Synthesis of N-decyl-1,
3-diaminopropanes and their structure properties for flotation of aluminosilicate minerals. Conserv. Util. Miner. Resour., 2002, 22(6), 33–37 (in Chinese).
15. Zhu, Y. M. Mineral flotation testing techniques: Measurement and application of reagents adsorption capacity on mineral surface. Non-Ferr. Min. Metall. 1988, 4(2), 10–14 (in Chinese).
16. Yao, T. Y., Yao, F. Y., Li, J. S. Adsorption and adsorption enthalpy of cationic surfactant on different sand stone surfaces. Oil Drill. Prod. Technol. 2008, 30(2), 82–85 (in Chinese).
17. Zang, H. C., Zang, L. X., Zhang, H., Wang, J. F., Yang, H. L., Jiang, W., Liu, D. M., Wang, F., Hu, T. Research progress on application of near-infrared spectroscopy in pharmaceuticals. Journal of Pharmaceutical Research 2014, 33, 125–128.