The organic-rich black shale in the Qiangtang Basin, northern Tibet, has long been the focus of petroleum geologists. This paper discusses the characteristics and maturity parameters of such biomarkers of the shale as n-alkanes, acyclic isoprenoids, terpenoids and steranes, using gas chromatographic (GS) and mass spectrometric (MS) techniques. n-Alkanes are characterized by a typical unimodal distribution, with dominant low carbon numbers of nC16–nC19, which suggests that the organic matter sources are mainly algae and planktonic organisms along with terrestrial higher plants. Furthermore, acyclic isoprenoid alkanes pristane (Pr) and phytane (Ph) are the most abundant, the Pr/Ph ratio being 0.06–0.70. The phytane dominance indicates that organic matter deposited in a reducing environment. In addition, the C3122S/(22S + 22R) hopanes ratio is 0.58– 0.59, that of C2920S/(20S + 20R) regular steranes 0.43–0.59, and αββ/(αββ + ααα) 0.39–0.65. These maturity parameters show that organic matter is in the maturity stage, while it is slightly more mature in the Biluocuo (BLC) section of the Qiangtang Basin than in the Ganbeixiama (GB) section. As indicated by the biomarkers values, the Jurassic source rocks in the two researched sections have a certain hydrocarbon potential.
1. Wang, C. S., Yi, H. S., Li, Y. Geology Evolution and Oil and Gas Prospect Evaluation of Qiangtang Basin in Tibet. Geological Publishing House, Beijing, 2001 (in Chinese with English abstract).
2. Zhao, Z. Z., Li, Y. T., Ye, H. F. Zhang, Y. W. Structural features and evolution of the Tibet plateau. Science Press, Beijing, 2001, 23–25 (in Chinese with English abstract).
3. Chen, L., Yi, H. S., Hu, R. Z., Zhong, H., Zou, Y. R. Organic geochemistry of the Early Jurassic oil shale from the Shuanghu area in Northern Tibet and the Early Toarcian Oceanic Anoxic Event. Acta Geol. Sin-Engl., 2005, 79(3), 392–397.
4. Chen, L., Yi, H. S., Tsai, L. L. Y., Xu, G. W., Da, X. J., Lin, A. T. S. The Jurassic black shales facies from Qiangtang basin (northern Tibet): Rare earth and trace elements for palaeoceanographic implications. Acta Geol. Sin-Engl., 2013, 87(2), 540–554.
5. Chen, L., Jenkyns, H. C., Xu, G. W., Mattioli, E., Da, X. J., Yi, H. S., Xia, M. Q. Zhu, Z. X., Huang, Z. H. Preliminary nanofossil and geochemical data from Jurassic black shale from the Qiangtang basin, northern Tibet. J. Asian Earth Sci., 2016, 115, 257–267.
https://doi.org/10.1016/j.jseaes.2015.10.004
6. Yi, H. S., Chen, L., Jenkyns, H. C., Da, X. J., Xia, M. Q., Xu, G. W., Ji, C. J. The Early Jurassic oil shales in the Qiangtang basin, northern Tibet: biomarkers and Toarcian Oceanic Anoxic Events. Oil Shale, 2013, 30(3), 441–455
https://doi.org/10.3176/oil.2013.3.05
7. Fu, X. G., Wang, J., Feng, X. L., Chen, W. B., Wang, D., Song, C. Y., Zeng, S. Q. Mineralogical composition of and trace-element accumulation in lower Toarcian anoxic sediments: a case study from the Bilong Co. oil shale, eastern Tethys. Geol. Mag., 2016, 153(4), 618–634.
https://doi.org/10.1017/S0016756815000758
8. Ji, C. J., Xia, G. Q., Yi, H. S., Wu, X. H., Li, Q. L., Mao, L. L., Fang, C. G. Aromatic hydrocarbons in the Biluo Co oil shale of the Shuanghu area, Northern Tibetan Plateau, and their implications. Oil Shale, 2014, 31(4), 351–364.
https://doi.org/10.3176/oil.2014.4.04
9. Wang, J., Tan, F. W., Li, Y. L., Li, Y. T., Chen, M., Wang, C. S., Guo, Z. J., Wang, X. L., Du, B. W., Zhu, Z. F. The Potential of the Oil and Gas Resources in Major Sedimentary Basins on the Qinghai-Xizang (Tibet) Plateau. Geological Publishing House, Beijing, 2004, 34–88 (in Chinese with English abstract).
10. Liu, Z. Q., Xu, X., Pan, G. T., Li, T. L., Yu, G. M., Yu, X. J., Jiang, X. Z., Wei, G. Y., Wang, C. S. Tectonics, Geological Evolution and Genetic Mechanism of Qinghai-Xizang Plateau. Geological Publishing House, Beijing, 1990 (in Chinese with English abstract).
11. Yu, G. M., Wang, C. S. Sedimentary Geology of the Xizang (Tibet) Tethys. Geological Publishing House, Beijing, 1990 (in Chinese with English abstract).
12. Matte, P., Tapponnier, P., Arnaud, N., Bourjot, L., Avouac, J. P., Vidal, P., Liu, Q., Pan, Y. S., Wang, Y. Tectonics of Western Tibet, between the Tarim and the Indus. Earth. Planet. Sc. Lett., 1996, 142(3–4), 311–330.
https://doi.org/10.1016/0012-821X(96)00086-6
13. Li, C., He, Z. H., Yang, D. M. The Problems of Geological tectonics in the Qiangtang Area, Tibet. Global Geology, 1996, 15(3), 18–23 (in Chinese with English abstract).
14. Jiang, M. Z., Wang, H. W. Aeromagnetic anomaly character in Qiangtang basin, northern Tibet. Geological Science and Technology Information, 2001, 20(2), 95–99 (in Chinese with English abstract).
15. Yi, H. S., Lin, J. H., Zhao, B., Li, Y., Shi, H., Zhu, L. D. New biostratigraphic data of the Qiangtang area in the northern Tibetan plateau. Geological Review, 2003, 49(1), 59–65 (in Chinese with English abstract).
16. Yin, J. R., Gao, J. H., Wang, Y. S., Zhang, S. Q., Zheng, C. Z., Xu, De. B., Bai, Z. D., Sun, X. Jurassic ammonites in anoxic black shales from Sewa and Anduo, Northern Tibet. Acta Palaeontologica Sinica, 2006, 45(3), 311–331 (in Chinese with English abstract).
17. Yin, J. R., Sun, L. X., Bai, Z. D., Xu, D. B., Zhang, X. J. New data on the Jurassic ammonites from the Shuanghu and Amdo areas, with comments on the Jurassic strata in north Tibet. Journal of Stratigraphy, 2005, 29(1), 7–15 (in Chinese with English abstract).
18. Wang, Y. S., Zheng, C. Z. Lithostratigraphy, sequence stratigraphy, and biostratigraphy of the Suobucha and Quse Formations and the Triassic-Jurassic boundary in the Sewa area on the south margin of the Qiangtang basin, northern Tibet. Journal of Stratigraphy, 2007, 31(4), 377–384 (in Chinese with English abstract).
19. Wang, Y. S., Zheng, C. Z. Gypsum beds of the early Jurassic Quse Formation in the Biloucuo area of the southern Qiangtang basin, northern Xizang. Journal of Stratigraphy, 2008, 32(3), 321–326 (in Chinese with English abstract).
20. Matsumoto, G. I., Akiyama, M., Watanuki, K., Torii, T. Unusual distributions of long-chain n-alkanes and n-alkenes in Antarctic soil. Org. Geochem., 1990, 15(4), 403–412.
https://doi.org/10.1016/0146-6380(90)90167-X
21. Ficken, K. J., Li, B., Swain, D. L., Eglinton, G. An n-alkane proxy for the sedimentary input of submerged/floating freshwater aquatic macrophytes. Org. Geochem., 2000, 31(7–8), 745–749.
https://doi.org/10.1016/S0146-6380(00)00081-4
22. Nott, C. J., Xie, S., Avsejs, L. A., Maddy, D., Chambers, F. M., Evershed, R. P. n-Alkane distributions in ombrotrophic mires as indicators of vegetation change related to climatic variation. Org. Geochem., 2000, 31(2–3), 231–235.
https://doi.org/10.1016/S0146-6380(99)00153-9
23. Bingham, E. M., McClymont, E. L., Väliranta, H., Mauquoy, D., Roberts, Z., Chambers, F. M., Pancost, R. D., Evershed, R. P. Conservative composition of n-alkane biomarkers in Sphagnum species: implications for paleoclimate reconstruction in ombrotrophic peat bogs. Org. Geochem., 2010, 41(2), 214–220.
https://doi.org/10.1016/j.orggeochem.2009.06.010
24. Rodriguez, N. D., Philp, R. P. Productivity and paleoclimatic controls on source rock character in the Aman Trough, north central Sumatra, Indonesia. Org. Geochem., 2012, 45, 18–28.
https://doi.org/10.1016/j.orggeochem.2012.01.004
25. Maxwell, J. R., Cox, R. E., Ackman, R. G., Hooper, S. N. The diagenesis and maturation of phytol. The stereochemistry of 2,6,10,14-tetramethylpentadecane from an ancient sediment. In: Advances in Organic Geochemistry (von Gaertner, H. R., Wehner, H., eds.), Pergamon Press, Oxford, 1972, 277–291.
26. Powell, T. G., McKirdy, D. M. Relationship between ratio of pristane to phytane, crude oil composition and geological environment in Australia. Nature, 1973, 243, 37–39.
https://doi.org/10.1038/physci243037a0
27. Sinninghe Damsté, J. P., Kenig, F., Koopmans, M. P., Köster, J. G., Schouten, S., Hayes, J. M., De Leeuw, J. W. Evidence for gammacerane as an indicator of water column stratification. Geochim. Cosmochim. Ac., 1995, 59(9), 1895–1900.
https://doi.org/10.1016/0016-7037(95)00073-9
28. Peters, K. E., Walters, C. C., Moldowan, J. M. The Biomarker Guide: II. Biomarkers and Isotopes in Petroleum Exploration and Earth History, 2nd ed. Cambridge University Press, Cambridge, 2005.
29. Rashby, S. E., Sessions, A. L., Summons, R. E., Newman, D. K. Biosynthesis of 2-methylbacteriohopanepolyols by an anoxygenic phototroph. Proc. Nat. Acad. Sci., 2007, 104(38), 15099–15104.
https://doi.org/10.1073/pnas.0704912104
30. Aquino Neto, F. R., Trendel, J. M., Restle, A., Connan, J., Albrecht, P. A. Occurrence and formation of tricyclic and tetracyclic terpanes in sediments and petroleums. In: Advances in Organic Geochemistry 1981 (Bjorøy, M. et al., eds.). Wiley and Sons, London, 1983, 659–667.
31. Huang, W. Y., Meinschein, W. G. Sterols as ecological indicators. Geochim. Cosmochim. Ac., 1979, 43(5), 739–745.
https://doi.org/10.1016/0016-7037(79)90257-6
32. Volkman, J. K. Sterols and other triterpenoids: source specificity and evolution of biosynthetic pathways. Org. Geochem., 2005, 36(2), 139–159.
https://doi.org/10.1016/j.orggeochem.2004.06.013
33. Seifert, W. K., Moldowan, J. M. Paleoreconstruction by biological markers. Geochim. Cosmochim. Ac., 1981, 45(6), 783–794.
https://doi.org/10.1016/0016-7037(81)90108-3
34. Sachse, V. F., Littke, R., Jabour, H., Schümann, T., Kluth, O. Late Cretaceous (Late Turonian, Coniacian and Santonian) petroleum source rocks as part of an OAE, Tarfaya Basin, Morocco. Mar. Petrol. Geol., 2012, 29(1), 35–49.
https://doi.org/10.1016/j.marpetgeo.2011.08.014
35. Blumenberg, M., Thiel, V., Riegel, W., Kah, L. C., Reitner, J. Biomarkers of black shales formed by microbial mats, Late Mesoproterozoic (1.1 Ga) Taoudeni Basin, Mauritania. Precambrian Res., 2012, 196–197, 113–127.
https://doi.org/10.1016/j.precamres.2011.11.010